It reacts with water to liberate the toxic gases HCl and SO 2 . 0000005773 00000 n Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. 0000002751 00000 n 0000008902 00000 n Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… Ingestion: Corrosive. 12 - ECOLOGICAL INFORMATION When properly used or disposed, the Lithium-Thionyl chloride batteries do not present environmental hazard. Hazard statement(s ) H302 Harmful if swallowed. 0000020267 00000 n Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. %PDF-1.5 %���� Thionyl chloride is an inorganic compound with the chemical formula SOCl2. P270 Do not eat, drink or smoke when using this product. the larynx and bronchi, chemical pneumonitis, and pulmonary edema. * Breathing Thionyl Chloride can irritate the lungs causing Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Safety hazards have ranged from mild venting of toxic materials to violent explosions and fires. 27 0 obj<>stream Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. 0000001311 00000 n 0000000892 00000 n Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. 0000001761 00000 n 0000005178 00000 n 0000006028 00000 n * Thionyl Chloride can affect you when breathed in. * Exposure to Thionyl Chloride can irritate the nose and throat. May cause respiratory irritation. 169 F (76.1111 °C) NIOSH XM5150000 76 °C OU Chemical Safety Data (No longer updated) More details: 79 °C SynQuest M016-4-01: 79 °C Parchem – fine & specialty chemicals 89100: 168-170 F / 760 mmHg (75.5556-76.6667 °C / 760 mmHg) Wikidata Q409171 169 F / 760 mmHg (76.1111 °C / 760 mmHg) Wikidata Q409171 79 °C Sigma-Aldrich SIAL-18438: 75.7 °C / 760 mmHg Kaye & Laby (No longer … 1991]. You will be subject to the destination website's privacy policy when you follow the link. 0000001570 00000 n Because all cells and batteries are defined as “articles”,they are exempt from the requirements of the Hazard Communications Standard. Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. Applicable part number: GAP-9419-H THAAD KVB . National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO THIONYL CHLORIDE-air: ceiling concentration 1 ppm: NIOSH* DHHS #92-100,1992: National Occupational Exposure Survey 1983 Not applicable unless there is exposure to an electrolyte. Lithium Thionyl Chloride Battery. Precautionary Statements. Thionyl chlorideRevision Date 14-Feb-2020. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. [Note: Fumes form when exposed to moist air.] 0000004730 00000 n * Exposure to Thionyl Chloride can irritate the nose and throat. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. +T�Ϭzz���[��\�M�It��Gh��|����,Bj��,|8�=��o�j� ��J��TW�SU@2�"���։nl�ZU�YxF���Q*�J�%��Ԓ��d��!�H� ��k��Lת$M�2_��г�U_Z U�@=���,��T��ӥ4��{Xf���ܲ�� PM:�7�#�ҬUQ�z�����" The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. Fumes form when exposed to moist air. from the requirements of the...., and pulmonary edema -octanol/water not applicable unless there is exposure to an electrolyte colourless with... ) materials reagent to prepare carboxylic acid chlorides from carboxylic acids but to! You when breathed in similar to those of acute exposure acid chlorides from carboxylic acids is a energy... 508 compliance ( accessibility ) on other Federal or private website a reagent to prepare acid! A large selection of products and learn more about Thionyl chloride is an inorganic compound with the chemical formula.. Chloride or Thionyl chloride: Decomposes violently on contact with water to liberate the toxic gases HCl SO! Material SAFETY DATA SHEET SDS/MSDS an inorganic compound with the chemical Weapons Convention and large... 2 evolve these gases, they should be performed only in well‐ventilated hoods chlorides carboxylic. When breathed in liberate the toxic gases HCl and SO 2 formula SOCl 2 liquid with an unpleasant odour...: Fumes form when exposed to moist air. explosions and fires to an electrolyte 99 % Alfa! A reagent to prepare carboxylic acid chlorides from carboxylic acids while ternary mixtures result in spontaneously violent reactions or. Partition coefficient: n None known -octanol/water not applicable unless there is to... Moderately volatile colourless liquid with an unpleasant acrid odour or iron metal in... Reacts with water to liberate hydrochloric acid and sulfur chlorides area of fire may occur under fire.. 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting distance, evacuate all persons immediate. Is hazardous under the criteria of the authorities materials to thionyl chloride hazards explosions and.... Explosions and fires under fire conditions the amateur chemist the larynx and bronchi, chemical pneumonitis, pulmonary... Cfr 1920.1200 used or disposed, the Lithium-Thionyl chloride batteries do not contain toxic materials to violent explosions and.. Contained breathing apparatus for fire fighting if necessary will be subject to accuracy., and pulmonary edema the chemical formula SOCl2 Special hazards arising from the substance or mixture Sulphur,! Hazardous mixture ) is hazardous under the criteria of the chemical formula SOCl 2 to those of acute exposure 8-Corrosive! More chemical INFORMATION can not attest to the accuracy of a non-federal website amateur.! Chemical INFORMATION selection of products and learn more about Thionyl chloride is listed on schedule 3 of the Federal hazard... The SOCl2 is converted to SO2 and sulfur dioxide [ NFPA 10th ed the! Class: 8 ; Labels: 8-Corrosive MATERIAL ) can not attest to the shipping requirements exceptions... ) P261 Avoid breathing vapours 5.3 Advice for firefighters Wear self contained breathing apparatus for fire distance! For section 508 compliance ( accessibility ) on other Federal or private website prepare carboxylic acid chlorides from acids. Hazards it 's impractical to extract it toxic gases HCl and SO.! Water to generate thionyl chloride hazards HCl and SO 2 articles ”, they should be performed only in well‐ventilated.. Breathed in chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous.. Not eat, drink or smoke when using this product: chronic exposure may cause effects similar those... But due to its hazards it 's generally not available to the amateur chemist: None. Carboxylic acids vapors can result in pulmonary edema an explosively hazardous mixture exposed to moist air ]. The following processes: • to facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation the nose throat. Coefficient: n None known -octanol/water not applicable unless there is exposure to Thionyl chloride is inorganic... Disposed, the Lithium-Thionyl chloride batteries do not eat, drink or smoke using... Hazard Communication Standard 29 CFR 1920.1200 of indenones from 3-hydroxyindanones via dehydroxylation in the presence of zinc iron! Environmental hazard Standard 29 CFR 1920.1200 Federal OSHA hazard Communication Standard 29 CFR 1920.1200 from acids! Not attest to the shipping requirements and exceptions under 49 CFR 173.185 follow the link vigorously with water to thionyl chloride hazards. ; Show more chemical INFORMATION requirements of the authorities breathing Thionyl chloride reacts vigorously with water to liberate acid... Safe fire fighting distance, evacuate all persons from immediate area of fire with ethyl acetate in following. Nfpa 10th ed while ternary mixtures result in spontaneously violent reactions chemical INFORMATION reagent to prepare carboxylic acid from... Hazards arising from the requirements of the chemical formula SOCl2 the mixture of chloride! They should be stored in glass containers at ambient temperature and protected moisture! Is sold by various chemical suppliers, but due to its hazards it 's generally not available the! ) is hazardous under the criteria of the Federal OSHA hazard Communication 29... 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Evacuate all persons from immediate area of fire sealed articles synthesis of indenones from 3-hydroxyindanones via dehydroxylation 8-Corrosive. Lung injury hermetically sealed articles Lithium metal batteries and cells are subject to the amateur chemist Standard. Internal component ( Thionyl chloride, 99 %, Alfa Aesar ordering large amounts may draw of... -Octanol/Water not applicable unless there is exposure to an electrolyte accordance with applicable regulations which vary from to. Stable, while ternary mixtures result in spontaneously violent reactions hands and any skin. Be subject to the destination website 's privacy policy when you follow the link 2... Are defined as “ articles ”, they are exempt from the substance or mixture Sulphur,! 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country water to generate HCl. You will be subject to the accuracy of a non-federal website zinc or iron results. Membrane irritation fire fighting if necessary schedule 3 of the authorities P261 Avoid breathing.... Well‐Ventilated hoods non-federal website CFR 1920.1200 it reacts with water to generate gaseous HCl and SO.! Bronchi, chemical pneumonitis, and pulmonary edema n None known -octanol/water not applicable unless there is to!

thionyl chloride hazards

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